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91.
92.
Shouko Nishida Masaya Shibano Hiroshi Kamitakahara Toshiyuki Takano 《International journal of molecular sciences》2015,16(12):29093-29102
We recently observed that the decanoylation of N-phenylthiocarbamoyl chitosan (2) with a mixture of decanoic anhydride and pyridine at 60 °C for 24 h afforded N,N-(decanoyl)phenythiocarbamoyl-/2-isothiocynato chitosan decanoate (3b) rather than the expected product N,N-(decanoyl)phenylthiocarbamoyl chitosan decanoate (3a). This result suggested that some of the N,N-(decanoyl)phenylthiocarmbamoyl groups had been converted to isothiocyanate groups during the decanoylation process. The subsequent reaction of compound 3b with aniline gave N,N-(decanoyl)phenylthiocarbamoyl/N-phenylthiocarbamoyl chitosan decanoate (4) in high yield. A solution of compound 4 in CHCl3 was then added to a solution of copper decanoate (5) in the same solvent, and the resulting mixture was cast onto a glass plate to give a cast film. The film was annealed at 200 °C in an oven to give a greenish film, which showed good near-infrared absorption characteristic in the range of 800–2200 nm. 相似文献
93.
Enhancement of the dissolution rate of the poorly water-soluble hypoglycemic agent, gliclazide, by the aid of lyophilization was investigated. Mannitol, sodium lauryl sulfate (SLS) and polyvinyl pyrrolidone (PVP-k-30) were employed in different weight ratios (43%, 56% and 64% w/w, respectively) as water-soluble excipients in the formulation. Lyophilized systems were found to exhibit extremely higher in vitro dissolution rate compared to the unprocessed drug powder. Solid state characterization of the lyophilized systems using X-ray powder diffraction, Fourier transform infrared spectroscopy and differential scanning calorimetry techniques revealed that dissolution enhancement was attributable to transformation of gliclazide from the crystalline to an amorphous state in the solid dispersion formed during the lyophilization process. The gastrointestinal absorption and hypoglycemic effect of the lyophilized gliclazide/SLS system were investigated following oral administration to Albino rabbits. Cmax and area under the plasma concentration–time curve of gliclazide (AUC0–12) after administration of the lyophilized formulations were significantly higher than those obtained after administration of the unprocessed gliclazide. 相似文献
94.
95.
H2S Reactive Absorption from Off‐Gas in a Spray Column: Insights from Experiments and Modeling 下载免费PDF全文
H2S removal from an off‐gas stream was performed in a spray column by H2S reactive absorption into a NaOH solution. The individual and interactive effects of three independent operating variables on the percentage of absorbed H2S were investigated: the initial pH of the scrubbing solution, the initial scrubbing solution temperature, and the volumetric liquid‐to‐gas ratio. The optimum operating variables were determined by response surface methodology (RSM) attaining a percentage of absorbed H2S of 98.7 ± 0.2 %. Additionally, the process performance was modeled by an artificial neural network (ANN) to predict the percentage of absorbed H2S. The results showed that the experimental data agreed better with the ANN model than with the RSM results. 相似文献
96.
基于溶液除湿热质传递过程中所遵循的质量平衡、能量平衡模型,以超声雾化溶液除湿系统(UADS)为例,探讨了在不同空气处理温度、湿度下,系统运行压力对除湿性能的影响。结果表明:随着运行压力的升高,UADS系统的除湿性能显著改善。特别是在所处理空气入口温度较高时,提升系统运行压力对除湿效率的提高作用更加显著。同时,当所处理空气的含湿量较大时,提高运行压力对系统除湿速率的增幅明显,而对除湿效率的改善作用减弱。此外,当除湿系统在较高压力下运行时,其除湿效率受所处理空气入口温湿度变化而产生的波动减小,系统性能稳定性显著改善。所得结果可对溶液除湿系统的高效、稳定运行提供积极参考。 相似文献
97.
以聚己内酯(PCL)为基体,添加不同含量聚乳酸(PLA)熔融共混制备具有不同分散相形态的PCL/PLA共混物,利用超临界二氧化碳(scCO2)微孔发泡工艺制备不同发泡倍率和开孔率的PCL/PLA多孔材料用于吸油应用。针对边长3 mm正方体样品溶解度实验发现100 min后CO2在PCL中已达到饱和吸附状态。PLA分散相含量的增加显著增大了PCL/PLA共混物泡孔密度,并使共混泡孔尺寸减小且分布更加均匀;发泡温度升高6℃,泡孔尺寸增大50%,发泡倍率增大38%,开孔率减小了20%。PCL/PLA开孔材料具有明显的亲油疏水性,发泡倍率越高,疏水性越好;针对花生油和硅油的吸油实验发现材料吸油率与发泡倍率和开孔率整体呈正比,实际吸油量高于理论计算值,10次循环吸油测试后样品吸油率仅降低8.5%,材料吸油量与油品特性黏度关系不大。 相似文献
98.
Qun He Dong Tian Hongliang Jiang Dengfeng Cao Shiqiang Wei Daobin Liu Pin Song Yue Lin Li Song 《Advanced materials (Deerfield Beach, Fla.)》2020,32(11):1906972
Developing efficient electrocatalysts for alkaline water electrolysis is central to substantial progress of alkaline hydrogen production. Herein, a Ni5P4 electrocatalyst incorporating single-atom Ru (Ni5P4-Ru) is synthesized through the filling of Ru3+ species into the metal vacancies of nickel hydroxides and subsequent phosphorization treatment. Electron paramagnetic resonance spectroscopy, X-ray-based measurements, and electron microscopy observations confirm the strong interaction between the nickel-vacancy defect and Ru cation, resulting in more than 3.83 wt% single-atom Ru incorporation in the obtained Ni5P4-Ru. The Ni5P4-Ru as an alkaline hydrogen evolution reaction catalyst achieves low onset potential of 17 mV and an overpotential of 54 mV at a current density of 10 mA cm-2 together with a small Tafel slope of 52.0 mV decade-1 and long-term stability. Further spectroscopy analyses combined with density functional theory calculations reveal that the doped Ru sites can cause localized structure polarization, which brings the low energy barrier for water dissociation on Ru site and the optimized hydrogen adsorption free energy on the interstitial site, well rationalizing the experimental reactivity. 相似文献
99.
100.
介绍一种工作在3~30 MHz的宽带、圆极化、高仰角、短波小型化天线。天线以对数螺旋线为基本结构,具有底端RLC集总元件的复合加载结构,并采用矩量法进行天线设计和优化。天线尺寸在25 m×25 m×10 m范围内。实践表明,该天线具有占地小、架设简便、效率高、200 km范围内无盲区等优点,可广泛应用于短波机动通信领域。 相似文献